Abstract To explore the feasibility of organic sulfur removal using organic acids, oxalic acid, citric acid and ascorbic acid were selected as desulfurization reagents. Combined with microwave irradiation technology, desulfurization experiments of highsulfur coal treated with nitric acid were conducted. The orthogonal experimental results showed that the microwave synergistic citric acid ...
The present work describes the desulfurization of coal using mildly reductive method. Both a Yanzhou and a Yanshan coal (referred to as YZ and YS coal, respectively), were treated in an aqueous media employing sodium borohydride (NaBH 4) as reducing agent, which is a well known hydrogen variables investigated include concentration of reductant, time, pH of initial media ...
Before and after the desulfurization process; total sulfur, pyritic sulfur, carbon content and calorific value were measured. The highest removal efficiencies of total sulfur and pyritic sulfur for Burdur coal obtained as 41% and 67%, for Tunçbilek coal obtained as 41% and 35%, and for Ermenek coal obtained as 47% and 41%, respectively.
In addition, the photocatalytic desulfurization process has little effect on the heat value of coal. On a basis of TGDSCDDSC analysis, it is found that the calorific value of the coal after photocatalytic desulfurization was slightly changed and the low temperature oxidation tendency was decreased which is helpful for desulfurized coal storage.
Physical desulfurization methods can only remove inorganic sulfur and are economical and practical in nature. 14,15 Highgradient magnetic separation technology is an effective method for physical desulfurization, which can be used to deal with fine particles of paramagnetic minerals and is applied to the desulfurization of fine coal (mainly ...
The combined effect of desulfurization and ash removal in the process of coal desulfurization by microwave with peroxyacetic acid was determined by evaluating variations in minerals and sulfur forms using Xray diffraction and Xray photoelectron spectroscopy. Dielectric properties of minerals or organic sulfur functional groups in coal were studied utilizing a vector network analyzer in the ...
An effective precombustion coal desulfurization process should ideally be capable of removing both organic and inorganic sulfur. A variety of techniques exist for the removal of inorganic sulfur from coal, but there is currently no costeffective method for the precombustion removal of organic sulfur. Recent developments have demonstrated ...
During the desulfurization process of coalfired power plants, there are many related parameters that affect the desulfurization efficiency. So it is very difficult to measure the desulfurization efficiency directly. In this paper, in order to reflect the relationship between monitoring process parameters and desulfurization efficiency better, a novel prediction model of desulfurization ...
Coal desulfurization The development and utilization of traditional coal plays a vital role in promoting social and economic development, but it has brought irreversible pollution to the ecological environment ( Zeng et al., 2021 ).
Coal desulfurization is imperative to create clean coal and reducing harmful emissions during the combustion process. However, organic sulfur in coal is more difficult to remove than inorganic sulfur. Therefore, in this paper, a method of coal sample desulfurization using citric acid with microwave assisted was proposed, and experimental ...
In this work, the desulfurization process of highsulfur anthracite coal is discussed, and the desulfurization method of "reduced iron powder + heat treatment + magnetic separation" (named "RIHM") is designed. ... In this study, a highsulfur coal desulfurization experiment was carried out for highsulfur raw coal to reveal the internal ...
The increasing use of highsulfur coal contradicts with the stringent environmental pressure in metallurgical industry. Microwave has been confirmed to have efficient effect for coal desulfurization. However, the removal behavior of thiophenic sulfur, as the most difficult sulfur to remove from coal, is still unclear in microwave field. In this work, the feasibility of removing thiophenic ...
In order to achieve better desulfurization effect, the researchers employ methods of adding chemical additives such as acid, alkali, oxidant, reductant, or changing the reaction atmosphere, or combining with other methods such as magnetic separation, ultrasonic and microorganism.
The major coal desulphurization technologies prior to combustion are physical coal cleaning, chemical and biological methods. Each has some technical and economical limitations. Physical coal cleaning can only remove limited amount of inorganic sulphur due to insufficient liberation.
In addition, the sulfur content of the raw coal reduces from % to %, total desulfurization rate of %, whose organic sulfur desulfurization is % after coal in shake flask experiments. And the desulfurization rate approaches the maximum value on the tenth day (from Figure 2B). It was demonstrated that strain SX12 could ...
As a typical industrial byproduct during the flue gas desulfurization process of coalfired, flue gas desulfurization ash (FGDA) with alkali mineral can facilitate the water damage resistance of asphalt mixtures. However, low density and high hydrophilic coefficient of FGDA limit its improvement effect. Hence, the comprehensive moisture ...
Fluegas desulfurization (FGD) material is a product of a process typically used for reducing SO 2 emissions from the exhaust gas system of a coalfired boiler. The physical nature of these materials varies from a wet sludge to a dry, powdered material depending on the process.
Desulfurization of Coal by Pyrolysis and Hydropyrolysis with Addition of KOH/NaOH Quanrun Liu, Haoquan Hu, Shengwei Zhu, Qiang Zhou, Wenying Li, Xianyong Wei, and Kechang Xie View Author Information Cite this: Energy Fuels 2005, 19, 4, Publication Date: April 23, 2005 https:////ef
Flotation desulfurization is the process of separating sulfur from coal samples into tailing products based on the differences in the physical and chemical properties of the mineral surfaces without changing the original sulfur content of the entire coal. ... and {111} facets in alk. soln., which is beneficial to the coal desulfurization. These ...
Most of the effective coal desulfurization techniques are based on chemical methods. Main desulfurization methods are chemical desulfurization, leaching, extraction, flotation, oxydesulfurization and biodesulfurization. The alkaline desulfurization is more effective in removing the pyritic sulfur from the coal, which is the less abundant form ...
The coal hydrogen production process requires hightemperature steam as a reactant. Coalfired boilers are usually used to provide hightemperature steam. The ammoniabased desulphurization process is an effective technology to remove SO2 in the coalfired flue gas. However, the mass transfer coefficient of SO2 in such an engineered process is not readily available in the literature. In this ...
The study aims to develop a thorough understanding of the desulfurization process and establish a theoretical framework for advancing clean coal technology and efficient coal utilization. Stringent control was maintained over parameters such as particle size, pretreatment time, bacterial species, and bacterial concentration.
XANES was used to analyze the change of sulfur forms in the desulfurization process of high organic sulfur coal under microwave heating and conventional heating conditions. The effects of microwave fields on the molecular properties, bond strength and reaction kinetic of organic sulfurcontaining groups were studied by quantum chemical calculation.
In coal combustion, to generate electric power and process heat, the sulfur is emitted as SO2, which is seen as one of the main causes of acid rain. This effect has led to an interest in the three main methods of removing coal sulfur: coal cleaning, inbed desulfurization, and flue gas desulfurization. Coal cleaning includes physical, chemical,
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